95364
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95364
Fluka
(+)-Diisopropyl L -tartrate
purum, ≥98.0% (sum of enantiomers, GC)
| Synonym: | |
| CAS Number: | 2217-15-4 |
| Linear Formula: | [-CH(OH)CO2CH(CH3)2]2 |
| Molecular Weight: | 234.25 |
| Beilstein Registry Number: | 1727863 |
| EC Number: | 218-709-0 |
| MDL number: | MFCD00064450 |
Description
| Other Notes | Chiral catalyst used for the enantioselective epoxidation of allylic alcohols, Sharpless AE1; Auxiliary in chiral allylic boronates2,3; Catalytic trimethylsilyl-cyanation of aldehydes4 |
Properties
| grade | purum |
| assay | ≥98.0% (sum of enantiomers, GC) |
| optical activity | [α]20/D +16±1°, neat |
| refractive index | n |
| n | |
| bp | 152 °C/12 mmHg(lit.) |
| density | 1.114 g/mL at 25 °C(lit.) |
Safety
| Personal Protective Equipment | Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) |
| WGK Germany | 3 |
| RTECS | WW8100000 |
| Flash Point(F) | >230 °F |
| Flash Point(C) | >110 °C |
Related Products
| Replaced by | 229180, (+)-Diisopropyl |
References
| Cited Reference | 1. T. Katsuki, V.S. Martin Org. React. 48, 1, (1996) |
| 2. W.R. Roush et al. J. Org. Chem. 55, 4109, (1990) | |
| 3. J. Am. Chem. Soc. 112, 6339, (1990) | |
| 4. M. Hayashi et al. J. Chem. Soc., Chem. Commun., 1364, (1990) | |
| Beilstein | Beil. 3,II,331 |
| reference | Aldrich MSDS 1, 724:D / Corp MSDS 1 (1), 1299:D / FT-IR 2 (1), 1087:A / FT-IR 1 (1), 664:A / FT-NMR 1 (1), 1042:B / NMR-Reference 2 (1), 559:C / RegBook 1 (1), 753:B / Sax 6, 1090 / Structure Index 1, 116:C:5 / Vapor Phase 3, 719:A |
